Design principles of perovskites for solar-driven thermochemical splitting of CO2Electronic supplementary information (ESI) available. See DOI: 10.1039/c7ta02081c

Perovskites are attractive redox materials for thermo/electrochemical fuel synthesis. To design perovskites with balanced redox energetics for thermochemically splitting CO 2 , the activity of lattice oxygen vacancies and stability against crystal phase changes and detrimental carbonate formation are predicted for a representative range of perovskites by electronic structure computations. Systematic trends in these materials properties when doping with selected metal cations are described in the free energy range defined for isothermal and temperature-swing redox cycles. To confirm that the predicted materials properties root in the bulk chemical composition, selected perovskites are synthesized and characterized by X-ray diffraction, transmission electron microscopy, and thermogravimetric analysis. On one hand, due to the oxidation equilibrium, none of the investigated compositions outperforms non-stoichiometric ceria - the benchmark redox material for CO 2 splitting with temperature-swings in the range of 800-1500 °C. On the other hand, certain promising perovskites remain redox-active at relatively low oxide reduction temperatures at which ceria is redox-inactive. This trade-off in the redox energetics is established for YFeO 3 , YCo 0.5 Fe 0.5 O 3 and LaFe 0.5 Ni 0.5 O 3 , identified as stable against phase changes and capable to convert CO 2 to CO at 600 °C and 10 mbar CO in CO 2 , and to being decomposed at 1400 °C and 0.1 mbar O 2 with an enthalpy change of 440-630 kJ mol −1 O 2 . Highly attractive and versatile metal oxides for thermo- and electrochemical fuel synthesis, perovskites are designed by balancing the redox thermodynamics for thermochemical spitting of CO 2 into separate streams of CO and O 2 .