Retracted Article: Spatially resolved mechanical properties of photo-responsive azobenzene-based supramolecular gels

The viscoelastic and stiffness properties of azobenzene-based supramolecular gels have been investigated by rheometry and AFM. Interestingly, the viscoelastic properties of cis -isomers were 810 fold enhanced in comparison to the trans -isomer, which was a unique phenomenon. More interestingly, Youn...

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Veröffentlicht in:RSC advances 2017-01, Vol.7 (43), p.26827-26833
Hauptverfasser: Mun, Gyuri, Choi, Heekyoung, Im, Nayoung, Ahn, Junho, Park, Jaehyeon, Seo, Hyowon, Choi, Yeonweon, Lee, Ji Ha, Jung, Jong Hwa
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Sprache:eng
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Zusammenfassung:The viscoelastic and stiffness properties of azobenzene-based supramolecular gels have been investigated by rheometry and AFM. Interestingly, the viscoelastic properties of cis -isomers were 810 fold enhanced in comparison to the trans -isomer, which was a unique phenomenon. More interestingly, Young's modulus of gels increased linearly with time of UV irradiation. The stiffness of gels was finely controlled in the spatial micro-scale environment. The improved mechanical strength was attributed to electrostatic interaction with the production of radicals of the gelators. The mechanical properties of azobenzene-based gelators were finely controlled by UV irradiation.
ISSN:2046-2069
2046-2069
DOI:10.1039/c7ra03797j