Time-evolved, far-red, circularly polarised luminescent polymer aggregates endowed with sacrificial helical Si-Si bond polymersElectronic supplementary information (ESI) available: Experimental section, CPL/PL/CD/UV-Vis spectra, DFT/TD-DFT-calculations, photographs of the colour change and characterisation of F8DBT by 1H-NMR. See DOI: 10.1039/c7qm00096k

An enantiomeric pair of non-charged, helical dialkylpolysilanes ( PSi- R and PSi- S ) were endowed with circularly polarised luminescence (CPL) at 700 nm and circular dichroism (CD) at 660 nm when non-helical poly{[dioctylfluorene]- alt -[bis(thiophenyl)-benzothiazole]} ( PF8DBT ) formed a hetero-ag...

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Hauptverfasser: Fujiki, Michiya, Yoshimoto, Shosei
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Sprache:eng
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