Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligandElectronic supplementary information (ESI) available: Preparation of L1 and complexes, spectroscopic and X-ray diffraction data. CCDC 1582379-1582381. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt04449f

Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic Zn II /Pd II , Pb II /Pd II and Cu II /Pd II complexes in high yielding stepwise or one pot reactions. The catalytic activity of these complexes in Heck coupling and Miyaura borylation reactions was investigated. Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic Zn II /Pd II , Pb II /Pd II and Cu II /Pd II complexes in high yielding stepwise or one pot reactions.