Direct synthesis of hydrothermally stable Ge-IWR zeolitesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7dt01087g

The poor hydrothermal stability of germanosilicate zeolites greatly retards their industrial application. Herein, we present a direct synthesis of Ge-containing IWR zeolites with outstanding hydrothermal stability. A simple quaternary ammonium cation, diethyldimethylammonium, was used as the structure-directing agent for the first time. The structure and chemical composition of the framework was studied by performing Rietveld refinement of XRD data combined with electron microscopy, thermogravimetric and chemical analysis techniques. Al-free and Al-containing IWR zeolites were subjected to high-temperature vapor (973 K, 4 h), water-immersion (room temperature, 12 h) and treatment with 65% HNO 3 solution (423 K, 24 h) to test their hydrothermal stability. Materials before and after hydrothermal treatments were characterized by complementary methods (XRD, FTIR, NMR and N 2 sorption). The set of experimental data unambiguously proves the high stability of the zeolite framework. A direct synthesis of hydrothermally stable Ge-containing IWR zeolites is achieved by using the diethyldimethylammonium cation as the structure-directing agent.