Palladium-catalyzed C-H activation/C-C cross-coupling reactions electrochemistry

Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electr...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-11, Vol.53 (9), p.12189-12192
Hauptverfasser: Ma, Cong, Zhao, Chuan-Qi, Li, Yi-Qian, Zhang, Li-Pu, Xu, Xue-Tao, Zhang, Kun, Mei, Tian-Sheng
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container_issue 9
container_start_page 12189
container_title Chemical communications (Cambridge, England)
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creator Ma, Cong
Zhao, Chuan-Qi
Li, Yi-Qian
Zhang, Li-Pu
Xu, Xue-Tao
Zhang, Kun
Mei, Tian-Sheng
description Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation. Palladium-catalyzed C(sp 2 )-H methylation and acylation via anodic oxidation have been developed to avoid the use of stoichiometric chemical oxidants.
doi_str_mv 10.1039/c7cc07429h
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title Palladium-catalyzed C-H activation/C-C cross-coupling reactions electrochemistry
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