Palladium-catalyzed C-H activation/C-C cross-coupling reactions electrochemistry

Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electr...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-11, Vol.53 (9), p.12189-12192
Hauptverfasser: Ma, Cong, Zhao, Chuan-Qi, Li, Yi-Qian, Zhang, Li-Pu, Xu, Xue-Tao, Zhang, Kun, Mei, Tian-Sheng
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Zusammenfassung:Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation. Palladium-catalyzed C(sp 2 )-H methylation and acylation via anodic oxidation have been developed to avoid the use of stoichiometric chemical oxidants.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc07429h