Palladium-catalyzed C-H activation/C-C cross-coupling reactions electrochemistry
Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electr...
Gespeichert in:
Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2017-11, Vol.53 (9), p.12189-12192 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation.
Palladium-catalyzed C(sp
2
)-H methylation and acylation
via
anodic oxidation have been developed to avoid the use of stoichiometric chemical oxidants. |
---|---|
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c7cc07429h |