Influence of Ca-doping in layered perovskite PrBaCo2O5+δ on the phase transition and cathodic performance of a solid oxide fuel cellElectronic supplementary information (ESI) available. See DOI: 10.1039/c6ta00746e

Layered perovskite oxides with the formula LnBaCo 2 O 5+ δ (Ln = Pr, Nd, Sm and Gd) have received attention as promising cathode materials for solid oxide fuel cells (SOFCs) because of their high oxygen diffusion and surface exchange coefficients. Recently, many researchers have reported that substituting barium with strontium or calcium can increase the structural stability, electrical conductivity, and catalytic activity of LnBaCo 2 O 5+ δ . In this study, we investigated the effect of Ca doping on the structural, electrical, and electrochemical properties of PrBa 1− x Ca x Co 2 O 5+ δ ( x = 0, 0.1, 0.2, 0.3 and 0.4). Increasing the amount of Ca dopant changed the structure of PrBa 1− x Ca x Co 2 O 5+ δ from a layered perovskite to a simple perovskite. At x = 0.3, co-existence of the simple and the layered perovskite structure is observed. Electrical conductivity and electro-chemical performance were improved with increasing amount of Ca in the layered perovskite structure and declined with increasing amount of the simple perovskite phase. We investigated the phase transition and its correlated electrical and electro-chemical properties of a novel double perovskite series, PrBa 1− x Ca x Co 2 O 5+ δ .