Synthesis and characterization of trinuclear N-heterocyclic carbene-palladium(ii) complexes and their applications in the Suzuki-Miyaura cross-coupling reactionElectronic supplementary information (ESI) available: 1H NMR and 13C NMR spectra of the trinuclear palladium(ii) complexes 5a-e, the catalysis products 8 and 10, characterization data of the catalysis products 8 and 10, and CIF files for the Pd complex 5d. CCDC 1472981. For ESI and crystallographic data in CIF or other electronic format s

Five novel trinuclear N-heterocyclic carbene-palladium( ii ) complexes 5a-e were conveniently synthesized through one-pot reactions of imidazolium salts, tridentate N-heterocycles {tris(4-(pyridin-4-yl)phenyl)amine or tris(4-(pyridin-3-yl)phenyl)amine} and palladium chloride in one step. All of the new complexes have been fully characterized by elemental analysis, 1 H, 13 C NMR, and IR spectra. Among them, the molecular structures of complex 5d have been determined by X-ray single-crystal diffraction. Moreover, the obtained trinuclear palladium( ii ) complexes were the effective catalyst precursors for the Suzuki-Miyaura coupling of aryl as well as benzyl chlorides with arylboronic acids. Under the optimal reaction conditions, the expected biaryl products were obtained in good to almost quantitative yields. Five novel trinuclear N-heterocyclic carbene-palladium( ii ) complexes 5a-e were conveniently synthesized in one step. The obtained palladium( ii ) complexes were the effective catalyst precursors for the Suzuki-Miyaura coupling.