Performance improvement by alumina coatings on YAlO:Ce phosphor powder deposited using atomic layer deposition in a fluidized bed reactor

To improve the thermal stability, Al 2 O 3 has been successfully coated on a Y 3 Al 5 O 12 :Ce 3+ (YAG:Ce) phosphor powder host by using the Atomic Layer Deposition (ALD) approach in a fluidized bed reactor. Transmission Electron Microscopy (TEM) and Energy Dispersive X-ray spectroscopy (EDX) analys...

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Veröffentlicht in:RSC advances 2016-08, Vol.6 (8), p.76454-76462
Hauptverfasser: Zhou, Zhi, Zhou, Nan, Lu, Xiangyang, Kate, Melvin ten, Valdesueiro, David, Ruud van Ommen, J, Hintzen, H. T. (Bert)
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Zusammenfassung:To improve the thermal stability, Al 2 O 3 has been successfully coated on a Y 3 Al 5 O 12 :Ce 3+ (YAG:Ce) phosphor powder host by using the Atomic Layer Deposition (ALD) approach in a fluidized bed reactor. Transmission Electron Microscopy (TEM) and Energy Dispersive X-ray spectroscopy (EDX) analysis indicate that coating an Al 2 O 3 thin layer by ALD is highly feasible. The luminescence properties (such as excitation and emission as well as quantum efficiency and UV-absorption of the coated YAG:Ce phosphor) were systematically analysed, with the further examination of the thermal resistance characteristics. The Al 2 O 3 thin layer coating with precisely controlled thickness by ALD can obviously improve the luminescence intensity and greatly enhances the thermal stability of the YAG:Ce phosphor. It is suggested that the alumina coating with tailoring thickness seems not only to act like a barrier to decrease the thermal quenching, but also as a great help to promote the light absorption and transfer. To improve the thermal stability, Al 2 O 3 has been successfully coated on a Y 3 Al 5 O 12 :Ce 3+ (YAG:Ce) phosphor powder host by using the Atomic Layer Deposition (ALD) approach in a fluidized bed reactor.
ISSN:2046-2069
DOI:10.1039/c6ra12983h