Novel luminescent β-ketoimine derivative of 2,1,3-benzothiadiazole: synthesis, complexation with Zn(ii) and photophysical properties in comparison with related compoundsElectronic supplementary information (ESI) available: Crystallographic data and additional figures. CCDC 1457754 (α-L2H), 1457755 (β-L2H), 1457756 (ZnL2). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6ra06547c
A novel β-ketoimine-functionalized 2,1,3-benzothiadiazole (4-(2,1,3-benzothiadiazole-4-ylamino)pent-3-en-2-one, L2H ) was synthesized and used as chelating ligand for the complexation with Zn( ii ) (complex ZnL2 ). The spectroscopic and photophysical properties of L2H and ZnL2 as well as those of pr...
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Sprache: | eng |
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Zusammenfassung: | A novel β-ketoimine-functionalized 2,1,3-benzothiadiazole (4-(2,1,3-benzothiadiazole-4-ylamino)pent-3-en-2-one,
L2H
) was synthesized and used as chelating ligand for the complexation with Zn(
ii
) (complex
ZnL2
). The spectroscopic and photophysical properties of
L2H
and
ZnL2
as well as those of previously described 4-amino-2,1,3-benzothiadiazole (
L1
) and its complex
ZnL1
have been thoroughly studied in the crystalline state and solution. The UV-Vis absorption spectra of free ligands
L1
,
L2H
and its deprotonated form
L2
−
, and complexes
ZnL1
and
ZnL2
were assigned on the basis of TD-DFT calculations. In contrast to
ZnL2
having conventional single-band fluorescence,
ZnL1
demonstrates a broad double-band purple-white fluorescence spanning the entire visible region. On the basis of careful spectroscopic studies the second band of this unusual fluorescence spectrum was attributed to the presence of traces of free ligand
L1
in the crystals of complex
ZnL1
. The energy transfer from the excited state of
ZnL1
to a free ligand
L1
was revealed.
2,1,3-Benzothiadiazoles and their Zn complexes show fluorescence in different wavelength regions, one of the complexes reveals white emission. |
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ISSN: | 2046-2069 |
DOI: | 10.1039/c6ra06547c |