A facile and practical copper diacetate mediated, ligand free C-N cross coupling of trivalent organobismuth compounds with amines and N-heteroarenes

In present work, an efficient Cu(OAc) 2 ·H 2 O catalyzed protocol in the absence of any additional ligand has been developed for the N -arylation of amines and nitrogen containing heterocycles using trivalent organobismuth reagents under mild conditions. This protocol tolerates a variety of function...

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Veröffentlicht in:	RSC advances 2016-01, Vol.6 (18), p.14531-14537
Hauptverfasser:	Jadhav, B. D, Pardeshi, S. K
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Sprache:	eng
Schlagworte:	Amines Copper Copper compounds Cross coupling Functional groups Ligands Reagents
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description	In present work, an efficient Cu(OAc) 2 ·H 2 O catalyzed protocol in the absence of any additional ligand has been developed for the N -arylation of amines and nitrogen containing heterocycles using trivalent organobismuth reagents under mild conditions. This protocol tolerates a variety of functional groups on amines and the organobismuth reagent with a high degree of chemoselectivity. In present work, an efficient Cu(OAc) 2 ·H 2 O catalyzed protocol in the absence of any additional ligand has been developed for the N -arylation of amines and nitrogen containing heterocycles using trivalent organobismuth reagents under mild conditions.
doi_str_mv	10.1039/c6ra00395h
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In present work, an efficient Cu(OAc) 2 ·H 2 O catalyzed protocol in the absence of any additional ligand has been developed for the N -arylation of amines and nitrogen containing heterocycles using trivalent organobismuth reagents under mild conditions.</description><subject>Amines</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Cross coupling</subject><subject>Functional groups</subject><subject>Ligands</subject><subject>Reagents</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkU1PwzAMhiMEEtPYhTtSjghRSPqRpcepAoaEhoTgXLmpuwW1TUlSEP-DH0y2IcAXv7Ye27JNyClnV5wl-bUSFlgQ2eaATGKWiihmIj_8p4_JzLlXFkxkPBZ8Qr4WtAGlW6TQ13SwoLxW0FJlhgEtrTUo9OCRdhi0x_qStnq9ZRuLSItoRZU1zoWCcWh1v6amod7qd2ix99TYwJpKu270m8B0gxn72tEPHULodI9uN3gVbdCjNWAxpE7IUQOtw9mPn5KX25vnYhk9PN7dF4uHSMVS-KipkAvFZZXnCU-5SDKBcSUZcGjqpBKyQsgbBBAJyrqqWF7HGciUyyyW2VwlU3K-7ztY8zai82WnncK2hR7N6EouGUvneZyzgF7s0d22FptysLoD-1lyVm6vXxbiabG7_jLAZ3vYOvXL_X0n-QZfqIPu</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Jadhav, B. 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In present work, an efficient Cu(OAc) 2 ·H 2 O catalyzed protocol in the absence of any additional ligand has been developed for the N -arylation of amines and nitrogen containing heterocycles using trivalent organobismuth reagents under mild conditions.</abstract><doi>10.1039/c6ra00395h</doi><tpages>7</tpages></addata></record>
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subjects	Amines Copper Copper compounds Cross coupling Functional groups Ligands Reagents
title	A facile and practical copper diacetate mediated, ligand free C-N cross coupling of trivalent organobismuth compounds with amines and N-heteroarenes
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