Aerobic copper-catalyzed decarboxylative thiolation

Copper-catalyzed decarboxylative thiolation using molecular oxygen as the sole oxidant was developed. A variety of aromatic carboxylic acids including 2-nitrobenzoic acids, pentafluorobenzoic acid and several heteroaromatic carboxylic acids undergo efficient thiolation to furnish the aryl sulfides i...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (56), p.8733-8736
Hauptverfasser: Li, Minghao, Hoover, Jessica M
Format: Artikel
Sprache:eng
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Zusammenfassung:Copper-catalyzed decarboxylative thiolation using molecular oxygen as the sole oxidant was developed. A variety of aromatic carboxylic acids including 2-nitrobenzoic acids, pentafluorobenzoic acid and several heteroaromatic carboxylic acids undergo efficient thiolation to furnish the aryl sulfides in moderate to excellent yields. A copper-catalyzed decarboxylative thiolation reaction to furnish aryl sulfides using molecular oxygen as the sole oxidant is described.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc04486g