Directly linked hydroporphyrin dimers

Directly linked hydroporphyrin dimers

Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded meso - meso -linked homo- and heterodimers, and meso -β-linked dimers. The photophysical...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (58), p.956-958
Hauptverfasser: Xiong, Ruisheng, Arkhypchuk, Anna I, Kovacs, Daniel, Orthaber, Andreas, Eszter Borbas, K
Format: Artikel
Sprache:eng
Schlagworte:
Coupling
Dimers
Electrochemical analysis
Organic Chemistry
Organisk kemi
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded meso - meso -linked homo- and heterodimers, and meso -β-linked dimers. The photophysical and electrochemical properties of the dimers are reported. The synthesis and chemical, photophysical and electrochemical characterisation of directly meso - meso - or meso -β-linked hydroporphyrin (chlorin) dimers is reported.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c6cc00516k