Roll-coating fabrication of ITO-free flexible solar cells based on a non-fullerene small molecule acceptor

We report organic solar cells (OSCs) with non-fullerene small molecule acceptors (SMAs) prepared in large area via a roll coating process. We employ all solution-processed indium tin oxide (ITO)-free flexible substrates for inverted solar cells with a new SMA of F(DPP) 2 B 2 . By utilizing poly(3-hexylthiophene) as donor blended with F(DPP) 2 B 2 as acceptor, ITO-free large-area flexible SMA based OSCs were produced under ambient conditions with the use of slot-die coating and flexographic printing methods on a lab-scale compact roll-coater that is readily transferrable to roll-to-roll processing. The effect of different processing solvents on the device performance was investigated, and the best performance with a power conversion efficiency of 0.65%, an open circuit voltage of 0.85 V, a short-circuit current density of 2.19 mA cm −2 , and a fill factor of 35% was obtained. Fully roll-coated ITO-free flexible organic solar cells based on a non-fullerene small molecule acceptor with a PCE of 0.65% were fabricated.