Manganese(iii)-mediated alkenyl Csp2-P bond formation from the reaction of β-nitrostyrenes with dialkyl phosphitesElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ob00404g

Mn(OAc) 3 -mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form ( E )-2-alkenyl phosphonates in good yield is described. Mn(OAc) 3 -mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form ( E )-2-alkenyl phosphonates is...

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Hauptverfasser: Xue, Jian-Fei, Zhou, Shao-Fang, Liu, Ye-Ye, Pan, Xiangqiang, Zou, Jian-Ping, Asekun, Olayinka Taiwo
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Sprache:eng
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Zusammenfassung:Mn(OAc) 3 -mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form ( E )-2-alkenyl phosphonates in good yield is described. Mn(OAc) 3 -mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form ( E )-2-alkenyl phosphonates is described.
ISSN:1477-0520
1477-0539
DOI:10.1039/c5ob00404g