High-throughput assessment of catalyst stability during autothermal reforming of model biogas
The long-term stability of Ni-based catalysts for autothermal reforming of model biogas has been assessed in a six parallel-flow reactor set-up implemented to test simultaneously six different catalysts at 700 °C under a feed consisting of 42% H 2 O, 14% CH 4 , 9% CO 2 , and 7% O 2 in argon. The rep...
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| Veröffentlicht in: | Catalysis science & technology 2015-01, Vol.5 (9), p.439-4397 |
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| creator | Luneau, M Schuurman, Y Meunier, F. C Mirodatos, C Guilhaume, N |
| description | The long-term stability of Ni-based catalysts for autothermal reforming of model biogas has been assessed in a six parallel-flow reactor set-up implemented to test simultaneously six different catalysts at 700 °C under a feed consisting of 42% H
2
O, 14% CH
4
, 9% CO
2
, and 7% O
2
in argon. The reproducibility of catalyst performance measured in the 6 parallel reactors was ascertained using a commercial Ni-based catalyst. A screening of 12 catalyst formulations identified 5-0.05 wt% Ni-Rh/MgAl
2
O
4
as a robust catalyst for autothermal reforming of model biogas over 200 h time-on-stream.
A six parallel-flow reactor set-up was implemented to assess the long-term stability of Ni-based catalysts for autothermal reforming of model biogas. |
| doi_str_mv | 10.1039/c5cy00702j |
| format | Article |
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2
O, 14% CH
4
, 9% CO
2
, and 7% O
2
in argon. The reproducibility of catalyst performance measured in the 6 parallel reactors was ascertained using a commercial Ni-based catalyst. A screening of 12 catalyst formulations identified 5-0.05 wt% Ni-Rh/MgAl
2
O
4
as a robust catalyst for autothermal reforming of model biogas over 200 h time-on-stream.
A six parallel-flow reactor set-up was implemented to assess the long-term stability of Ni-based catalysts for autothermal reforming of model biogas.</description><identifier>ISSN: 2044-4753</identifier><identifier>EISSN: 2044-4761</identifier><identifier>DOI: 10.1039/c5cy00702j</identifier><language>eng</language><publisher>Royal Society of Chemistry</publisher><subject>Biogas ; Carbon dioxide ; Catalysis ; Catalysts ; Chemical Sciences ; Environment and Society ; Environmental Sciences ; Nickel ; Reactors ; Reforming ; Reproducibility ; Stability</subject><ispartof>Catalysis science & technology, 2015-01, Vol.5 (9), p.439-4397</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c416t-ad3ff8b9261648a358df9ea7389aa36943d8588de986280ab59b73c824c103233</citedby><cites>FETCH-LOGICAL-c416t-ad3ff8b9261648a358df9ea7389aa36943d8588de986280ab59b73c824c103233</cites><orcidid>0000-0002-2936-0910 ; 0000-0001-8581-7260 ; 0000-0001-7953-2883</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27923,27924</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01198971$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Luneau, M</creatorcontrib><creatorcontrib>Schuurman, Y</creatorcontrib><creatorcontrib>Meunier, F. C</creatorcontrib><creatorcontrib>Mirodatos, C</creatorcontrib><creatorcontrib>Guilhaume, N</creatorcontrib><title>High-throughput assessment of catalyst stability during autothermal reforming of model biogas</title><title>Catalysis science & technology</title><description>The long-term stability of Ni-based catalysts for autothermal reforming of model biogas has been assessed in a six parallel-flow reactor set-up implemented to test simultaneously six different catalysts at 700 °C under a feed consisting of 42% H
2
O, 14% CH
4
, 9% CO
2
, and 7% O
2
in argon. The reproducibility of catalyst performance measured in the 6 parallel reactors was ascertained using a commercial Ni-based catalyst. A screening of 12 catalyst formulations identified 5-0.05 wt% Ni-Rh/MgAl
2
O
4
as a robust catalyst for autothermal reforming of model biogas over 200 h time-on-stream.
A six parallel-flow reactor set-up was implemented to assess the long-term stability of Ni-based catalysts for autothermal reforming of model biogas.</description><subject>Biogas</subject><subject>Carbon dioxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical Sciences</subject><subject>Environment and Society</subject><subject>Environmental Sciences</subject><subject>Nickel</subject><subject>Reactors</subject><subject>Reforming</subject><subject>Reproducibility</subject><subject>Stability</subject><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkcFOwzAMhiMEEtPYhTtSuQFSIWnaNDmiChhoEhc4cECRm6ZrpnYpSYq0t6djaNwQvtiyP1u2f4ROCb4mmIoblakNxjlOVgdokuA0jdOckcN9nNFjNPN-hUdLBcE8maD3uVk2cWicHZZNP4QIvNfed3odIltHCgK0Gx8iH6A0rQmbqBqcWS8jGIINjXYdtJHTtXXdNju2dLbSbVQauwR_go5qaL2e_fgper2_eynm8eL54bG4XcQqJSzEUNG65qVIGGEpB5rxqhYacsoFAGUipRXPOK-04CzhGMpMlDlVPEnVeHhC6RRd7uY20MremQ7cRlowcn67kNscJkRwkZNPMrIXO7Z39mPQPsjOeKXbFtbaDl6SnI50kmP2DxQLwtj2s1N0tUOVs96PD9mvQbDcqiOLrHj7VudphM92sPNqz_2qN9bP_6rLvqrpF7aElp8</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Luneau, M</creator><creator>Schuurman, Y</creator><creator>Meunier, F. C</creator><creator>Mirodatos, C</creator><creator>Guilhaume, N</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><scope>7SR</scope><scope>7TB</scope><scope>8BQ</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-2936-0910</orcidid><orcidid>https://orcid.org/0000-0001-8581-7260</orcidid><orcidid>https://orcid.org/0000-0001-7953-2883</orcidid></search><sort><creationdate>20150101</creationdate><title>High-throughput assessment of catalyst stability during autothermal reforming of model biogas</title><author>Luneau, M ; Schuurman, Y ; Meunier, F. C ; Mirodatos, C ; Guilhaume, N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c416t-ad3ff8b9261648a358df9ea7389aa36943d8588de986280ab59b73c824c103233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Biogas</topic><topic>Carbon dioxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical Sciences</topic><topic>Environment and Society</topic><topic>Environmental Sciences</topic><topic>Nickel</topic><topic>Reactors</topic><topic>Reforming</topic><topic>Reproducibility</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luneau, M</creatorcontrib><creatorcontrib>Schuurman, Y</creatorcontrib><creatorcontrib>Meunier, F. C</creatorcontrib><creatorcontrib>Mirodatos, C</creatorcontrib><creatorcontrib>Guilhaume, N</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luneau, M</au><au>Schuurman, Y</au><au>Meunier, F. C</au><au>Mirodatos, C</au><au>Guilhaume, N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-throughput assessment of catalyst stability during autothermal reforming of model biogas</atitle><jtitle>Catalysis science & technology</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>5</volume><issue>9</issue><spage>439</spage><epage>4397</epage><pages>439-4397</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>The long-term stability of Ni-based catalysts for autothermal reforming of model biogas has been assessed in a six parallel-flow reactor set-up implemented to test simultaneously six different catalysts at 700 °C under a feed consisting of 42% H
2
O, 14% CH
4
, 9% CO
2
, and 7% O
2
in argon. The reproducibility of catalyst performance measured in the 6 parallel reactors was ascertained using a commercial Ni-based catalyst. A screening of 12 catalyst formulations identified 5-0.05 wt% Ni-Rh/MgAl
2
O
4
as a robust catalyst for autothermal reforming of model biogas over 200 h time-on-stream.
A six parallel-flow reactor set-up was implemented to assess the long-term stability of Ni-based catalysts for autothermal reforming of model biogas.</abstract><pub>Royal Society of Chemistry</pub><doi>10.1039/c5cy00702j</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-2936-0910</orcidid><orcidid>https://orcid.org/0000-0001-8581-7260</orcidid><orcidid>https://orcid.org/0000-0001-7953-2883</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Catalysis science & technology, 2015-01, Vol.5 (9), p.439-4397 |
| issn | 2044-4753 2044-4761 |
| language | eng |
| recordid | cdi_rsc_primary_c5cy00702j |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Biogas Carbon dioxide Catalysis Catalysts Chemical Sciences Environment and Society Environmental Sciences Nickel Reactors Reforming Reproducibility Stability |
| title | High-throughput assessment of catalyst stability during autothermal reforming of model biogas |
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