Fluorescent aliphatic hyperbranched polyether: chromophore-free and without any N and P atoms

The strong fluorescence, in both the solution and the bulk state, of a chromophore-free aliphatic hyperbranched polyether which does not contain N and P atoms was reported for the first time. Effects of concentration and solvent solubility were measured. Its ethanol solution shows a strong blue-gree...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2016-02, Vol.18 (6), p.4295-4299
Hauptverfasser: Miao, Xuepei, Liu, Tuan, Zhang, Chen, Geng, Xinxin, Meng, Yan, Li, Xiaoyu
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Sprache:eng
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Zusammenfassung:The strong fluorescence, in both the solution and the bulk state, of a chromophore-free aliphatic hyperbranched polyether which does not contain N and P atoms was reported for the first time. Effects of concentration and solvent solubility were measured. Its ethanol solution shows a strong blue-green fluorescence ( Y u = 0.11-0.39), and its fluorescence shows a strong selective quenching with respect to Fe 3+ . An unusual fluorescent aliphatic hyperbranched polyether epoxy which does not have N and P atoms was reported for the first time.
ISSN:1463-9076
1463-9084
DOI:10.1039/c5cp07134h