Control of interpenetration in a microporous metal-organic framework for significantly enhanced CH/CO separation at room temperature
A novel non-interpenetrated three-dimensional porous metal-organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions. The resulting UTSA-68a shows a notably higher porosity and adsorption selectivity (3.5-5) for C 2 H 2 /CO 2 separation compared to that of doubl...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-02, Vol.52 (17), p.3494-3496 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
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| Zusammenfassung: | A novel non-interpenetrated three-dimensional porous metal-organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions. The resulting UTSA-68a shows a notably higher porosity and adsorption selectivity (3.5-5) for C
2
H
2
/CO
2
separation compared to that of doubly interpenetrated ZJU-30a (1.7-2.4) at room temperature.
A novel non-interpenetrated three-dimensional porous metal-organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c5cc10598f |