An electrochemical analyzer for in situ flow determination of Pb(ii) and Cd(ii) in lake water with on-line data transmission and a global positioning systemElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ay00012b

An electrochemical analyzer based on a potentiostat/galvanostat (PG004) was developed and applied to perform in situ Pb 2+ and Cd 2+ determination in water samples with on-line data transmission, and a global positioning system (GPS), to acquire the geographical coordinate of the place being monitored. For this, a flow-batch analysis (FBA) and a thermostated electrochemical flow cell (EFC) coupled with a boron-doped diamond electrode (BDD) were developed to measure these ions by employing square-wave anodic stripping voltammetry (SWASV). To study the Pb 2+ and Cd 2+ ions by in situ analysis, mainly for temperature variation, the PG004 was evaluated and the limits of detection were 0.08 μg L −1 and 0.18 μg L −1 , respectively, for simultaneous analysis. Then, the PG004 was used for in situ determination of analytes in lake water samples, and voltammograms with good resolution and low noise were obtained. Recoveries ranged from 93.3% to 109%, and the waste generated was as low as 700 μL per determination. The accuracy of the method was checked by determination of Cd 2+ and Pb 2+ in certified water (NIST), t -unpaired test was applied for n = 3, and the values found were in close agreement at a confidence level of 95%. Besides the geographical coordinates obtained by using a GPS receiver, and experimental data sent via wireless, the device used a solar board as renewable energy. The developed system proved to be a useful tool to measure Pb 2+ and Cd 2+ in lake samples with a fast, on-line, and environmentally friendly analytical method. A potentiostat/galvanostat with wireless data transmission and a GPS receiver was applied to in situ flow analyses.