Cobaltate anion couples terminal dienes with trifluoroacetic anhydride: a direct fluoroacylation of 1,3-dienesElectronic supplementary information (ESI) available. CCDC 991428. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc00743c

Perfluoroketones are useful products and intermediates in medicinal chemistry. Herein, cobalt-mediated fluoroacylation of 1,3-dienes is described using perfluorinated anhydrides such as TFAA. The reaction is thought to proceed through a fluoroacylcobalt reagent formed in situ . Perfluoroacylation of...

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Hauptverfasser:	Kohn, Benjamin L, Rovis, Tomislav
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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