Efficient green synthesis of bis(cyclic carbonate)poly(dimethylsiloxane) derivative using CO2 addition: a novel precursor for synthesis of urethanes

Poly(dimethyl siloxane), PDMS, with terminal cyclic carbonate groups was prepared by cycloaddition of carbon dioxide to epoxy rings using tetra alkyl-ammonium bromide as a catalyst under efficient and mild conditions. The process was carried out under a modest pressure of carbon dioxide ( i.e. ,