Chiral recognition with a benzofuran receptor that mimics an oxyanion holeElectronic supplementary information (ESI) available: Experimental procedures, 1H and 13C NMR, IR and HRMS spectra of compounds 1-8 and guests of Tables 2-4, modeling studies of Fig. 1 and 7 and X-ray diffraction data of compounds 6 and 7, determination of the absolute configuration of (+)-7 and (+)-8 by simulation of ECD spectra. CCDC 1010318-1010319. For ESI and crystallographic data in CIF or other electronic format see

A new chiral benzofuran receptor has been synthesized and its properties in the association of amino acid derivatives have been studied. X-ray structures were obtained and these corroborate the presence of an oxyanion-hole motif in these structures. Chiral resolution of a novel tripodal oxyanion-hol...

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Hauptverfasser: Fuentes de Arriba, Ángel L, Herrero, Ángel Gómez, Rubio, Omayra H, Monleón, Laura M, Simón Rubio, Luis, Alcázar, Victoria, Sanz, Francisca, Morán, Joaquín R
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Sprache:eng
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Zusammenfassung:A new chiral benzofuran receptor has been synthesized and its properties in the association of amino acid derivatives have been studied. X-ray structures were obtained and these corroborate the presence of an oxyanion-hole motif in these structures. Chiral resolution of a novel tripodal oxyanion-hole receptor with application in amino acid derivatives enantioselective extraction.
ISSN:1477-0520
1477-0539
DOI:10.1039/c4ob01954g