Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324Electronic supplementary information (ESI) available: Isolation experimental procedure, copies of 1 and 2D NMR spectra and DFT calculations. See DOI: 10.1039/c4cc05413j

Croton insularis introduces the seco-casbane class with EBC-329 and the first casbane endoperoxide EBC-324Electronic supplementary information (ESI) available: Isolation experimental procedure, copies of 1 and 2D NMR spectra and DFT calculations. See DOI: 10.1039/c4cc05413j

Investigation of Croton insularis afforded the first in class seco -casbane diterpene, EBC-329. A highly oxidised casbane, EBC-324, was also isolated. The structural motif within EBC-324, which consists of an epoxidised hemi-acetal endoperoxide, is new to the casbane family. Croton insularis unveile...

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Hauptverfasser: Maslovskaya, Lidiya A, Savchenko, Andrei I, Krenske, Elizabeth H, Gordon, Victoria A, Reddell, Paul W, Pierce, Carly J, Parsons, Peter G, Williams, Craig M
Format: Artikel
Sprache:eng
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Zusammenfassung:Investigation of Croton insularis afforded the first in class seco -casbane diterpene, EBC-329. A highly oxidised casbane, EBC-324, was also isolated. The structural motif within EBC-324, which consists of an epoxidised hemi-acetal endoperoxide, is new to the casbane family. Croton insularis unveiled the first seco -casbane diterpene EBC-329, along with EBC-324, which consists of an epoxidised hemi-acetal endoperoxide.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05413j