Selective oxidation of glycerol to lactic acid under acidic conditions using AuPd/TiO2 catalyst
The selective oxidation of glycerol was investigated using AuPd/TiO 2 as the catalyst in the presence of AlCl 3 , and lactic acid was obtained as the predominant product. It was demonstrated that AuPd/TiO 2 and AlCl 3 played synergistic roles in the production of lactic acid. The possible reaction p...
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Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (6), p.152-1525 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The selective oxidation of glycerol was investigated using AuPd/TiO
2
as the catalyst in the presence of AlCl
3
, and lactic acid was obtained as the predominant product. It was demonstrated that AuPd/TiO
2
and AlCl
3
played synergistic roles in the production of lactic acid. The possible reaction pathway was proposed, in which glycerol was first oxidized to glyceraldehyde and dihydroxyacetone, catalysed by AuPd/TiO
2
, followed by the formation of lactic acid, catalyzed by AlCl
3
.
The production of lactic acid from glycerol under acidic conditions was achieved
via
selective oxidation of glycerol catalysed by AuPd/TiO
2
combined with AlCl
3
. |
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ISSN: | 1463-9262 1463-9270 |
DOI: | 10.1039/c3gc40314a |