Selective oxidation of glycerol to lactic acid under acidic conditions using AuPd/TiO2 catalyst

The selective oxidation of glycerol was investigated using AuPd/TiO 2 as the catalyst in the presence of AlCl 3 , and lactic acid was obtained as the predominant product. It was demonstrated that AuPd/TiO 2 and AlCl 3 played synergistic roles in the production of lactic acid. The possible reaction p...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (6), p.152-1525
Hauptverfasser: Xu, Jilei, Zhang, Hongye, Zhao, Yanfei, Yu, Bo, Chen, Sha, Li, Yanbin, Hao, Leiduan, Liu, Zhimin
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The selective oxidation of glycerol was investigated using AuPd/TiO 2 as the catalyst in the presence of AlCl 3 , and lactic acid was obtained as the predominant product. It was demonstrated that AuPd/TiO 2 and AlCl 3 played synergistic roles in the production of lactic acid. The possible reaction pathway was proposed, in which glycerol was first oxidized to glyceraldehyde and dihydroxyacetone, catalysed by AuPd/TiO 2 , followed by the formation of lactic acid, catalyzed by AlCl 3 . The production of lactic acid from glycerol under acidic conditions was achieved via selective oxidation of glycerol catalysed by AuPd/TiO 2 combined with AlCl 3 .
ISSN:1463-9262
1463-9270
DOI:10.1039/c3gc40314a