Synthesis and characterization of an octanuclear copper() methanediide cluster
The reaction of [K{CH( i Pr 2 P&z.dbd;S) 2 (C 9 H 6 N-2)}] n ( 1 ) with one equivalent of CuCl in THF afforded a rare octanuclear copper( i ) methanediide cluster ( 3 ). The structure of compound 3 as determined by X-ray crystallography was found to have eight copper atoms that form a Gyrobifast...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2014-01, Vol.43 (1), p.63-66 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of [K{CH(
i
Pr
2
P&z.dbd;S)
2
(C
9
H
6
N-2)}]
n
(
1
) with one equivalent of CuCl in THF afforded a rare octanuclear copper(
i
) methanediide cluster (
3
). The structure of compound
3
as determined by X-ray crystallography was found to have eight copper atoms that form a Gyrobifastigium (J26).
The Gyrobifastigium organocopper(
i
) cluster
: The reaction of [K{CH(
i
Pr
2
P&z.dbd;S)
2
(C
9
H
6
N-2)}]
n
(
1
) with one equivalent of CuCl in THF afforded an extremely rare octanuclear copper(
i
) methanediide cluster (
3
). The structure of compound
3
has been characterized by X-ray crystallography and NMR spectroscopy. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c3dt52833b |