Sequential synthesis of β-amino alcohols using a CeO2-ZrO2 bifunctional catalyst systemElectronic supplementary information (ESI) available: experimental details and characterization data of selected products. See DOI: 10.1039/c3cy20806k
CeO 2 -ZrO 2 was explored as a bifunctional catalyst system for the synthesis of β-amino alcohols through epoxidation and subsequent aminolysis. Epoxidation of styrene to styrene oxide using t -butyl hydrogen peroxide (TBHP) as a green oxidant followed by subsequent aminolysis with diverse amines ga...
Gespeichert in:
Hauptverfasser: | , , , , |
---|---|
Format: | Artikel |
Sprache: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | CeO
2
-ZrO
2
was explored as a bifunctional catalyst system for the synthesis of β-amino alcohols through epoxidation and subsequent aminolysis. Epoxidation of styrene to styrene oxide using
t
-butyl hydrogen peroxide (TBHP) as a green oxidant followed by subsequent aminolysis with diverse amines gave the corresponding β-amino alcohols. CeO
2
-ZrO
2
was found to be a reusable and highly selective catalyst for both the epoxidation and aminolysis reactions.
CeO
2
-ZrO
2
was explored as a bifunctional catalyst system for the synthesis of β-amino alcohols through epoxidation and subsequent aminolysis. |
---|---|
ISSN: | 2044-4753 2044-4761 |
DOI: | 10.1039/c3cy20806k |