Stepwise addition of difluorocarbene to a transition metal centreElectronic supplementary information (ESI) available. CCDC 968287-968289. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc48468h
The Ruppert-Prakash reagent (Me 3 SiCF 3 ) is used to introduce difluorocarbene (CF 2 ) and tetrafluoroethylene (TFE) ligands to cobalt( i ) metal centres, whereby the TFE ligand is generated via [2+1] cycloaddition between [Co]&z.dbd;CF 2 and CF 2 . The Ruppert-Prakash reagent (Me 3 SiCF 3 ) is...
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| Format: | Artikel |
| Sprache: | eng |
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| Zusammenfassung: | The Ruppert-Prakash reagent (Me
3
SiCF
3
) is used to introduce difluorocarbene (CF
2
) and tetrafluoroethylene (TFE) ligands to cobalt(
i
) metal centres, whereby the TFE ligand is generated
via
[2+1] cycloaddition between [Co]&z.dbd;CF
2
and CF
2
.
The Ruppert-Prakash reagent (Me
3
SiCF
3
) is used to introduce difluorocarbene (CF
2
) and tetrafluoroethylene (TFE) ligands to cobalt(
i
) metal centres, whereby the TFE ligand is generated
via
[2+1] cycloaddition between [Co]&z.dbd;CF
2
and CF
2
. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c3cc48468h |