Organocatalyzed cascade reactions of carbohydrates - a direct access to C-glycosidesElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc48120d

Organocatalyzed cascade reactions of carbohydrates - a direct access to C-glycosidesElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc48120d

An organocatalyzed transformation to elongate unprotected carbohydrates is described. This operationally simple methodology is based on a Knoevenagel-oxa-Michael cascade. This reaction is catalyzed by proline and DBU. Products were obtained with exceptional high degrees of stereoselectivity. An orga...

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Hauptverfasser: Voigt, Benjamin, Mahrwald, Rainer
Format: Artikel
Sprache:eng
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Zusammenfassung:An organocatalyzed transformation to elongate unprotected carbohydrates is described. This operationally simple methodology is based on a Knoevenagel-oxa-Michael cascade. This reaction is catalyzed by proline and DBU. Products were obtained with exceptional high degrees of stereoselectivity. An organocatalyzed transformation to elongate unprotected carbohydrates is described.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48120d