Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation: new insight into the electronic structure of high-valent iron porphyrin complexesElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc40319j
UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N 3 ) 2 ], showing the Mössbauer parameters quite similar to those of the ferryl species of MauG, CytP450 BM3 , Cyt P450 CAM , and CPO, exists as equilibrium mixtures of Fe( iv ) porphyrin and Fe( iii ) porphyrin radical cation. UV-Vis,...
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| Format: | Artikel |
| Sprache: | eng |
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| Zusammenfassung: | UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N
3
)
2
], showing the Mössbauer parameters quite similar to those of the ferryl species of MauG, CytP450
BM3
, Cyt P450
CAM
, and CPO, exists as equilibrium mixtures of Fe(
iv
) porphyrin and Fe(
iii
) porphyrin radical cation.
UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N
3
)
2
] exists as equilibrium mixtures of Fe(
iv
) porphyrin and Fe(
iii
) porphyrin radical cation. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c3cc40319j |