A phenomenological theory of nonphotochemical laser induced nucleation

We present a theory of electric field driven phase transitions that occur via nucleation of needle-shaped, metallic particles. The predictions of this theory have much in common with the observations related to nonphotochemical laser induced nucleation (NPLIN). That connection is rather paradoxical because the final NPLIN products are dielectric crystals. By elaborating on the unique features of field induced transitions and the complexities of liquid systems, we discuss how our theory may provide some insight into the open question of the NPLIN mechanism. A qualitative description of the post nucleation stage and conjectures about the microscopic nature of the metallic particles in liquids are also provided. Electric field driven phase transitions can occur via nucleation of elongated, metallic embryos even when the metal phase is unstable.