Unsupported single-walled water cluster nanotube: A novel hydrogen bonding pattern for water organizationCCDC reference number 878399. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c2ce25647a

An unprecedented single-walled nanotube organization of water spontaneously forms in the crystal lattice of a discrete Pd II ,Pt II 9-methyladenine complex: [(dien)Pd( N1 -9-MeA- N7 )Pt(NH 3 ) 3 ](ClO 4 ) 4 ·9.33H 2 O. Structural details of this unsupported self-assembled water architecture and its novel hydrogen bonding pattern are reported. An unsupported single-walled water cluster nanotube organization self-assembles in the crystal lattice of a discrete Pd II ,Pt II 9-methyladenine complex.