CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactionsElectronic supplementary information (ESI) available: Details of experiments, techniques, and structures; Tables S1-S5; Fig. S1-S9. CCDC 895508-895511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2cc36153a

CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactionsElectronic supplementary information (ESI) available: Details of experiments, techniques, and structures; Tables S1-S5; Fig. S1-S9. CCDC 895508-895511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2cc36153a

A porous one-dimensional coordination chain compound, [Ru 2 ( p -F-PhCO 2 ) 4 (phz)] ( 1′ ; p -F-PhCO 2 − = para -fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO 2 at 195 K in a stepwise sorption manner. A porous one-dimensional chain co...

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Hauptverfasser: Kosaka, Wataru, Yamagishi, Kayo, Yoshida, Hiroki, Matsuda, Ryotaro, Kitagawa, Susumu, Takata, Masaki, Miyasaka, Hitoshi
Format: Artikel
Sprache:eng
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Zusammenfassung:A porous one-dimensional coordination chain compound, [Ru 2 ( p -F-PhCO 2 ) 4 (phz)] ( 1′ ; p -F-PhCO 2 − = para -fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO 2 at 195 K in a stepwise sorption manner. A porous one-dimensional chain compound composed of paddlewheel [Ru 2 II,II ] units bridged by phenazine specifically adsorbs CO 2 at 195 K in a stepwise sorption manner.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc36153a