Catalysis-based enantioselective total synthesis of myxothiazole Z, (14S)-melithiazole G and (14S)-cystothiazole FElectronic supplementary information (ESI) available: Details of experimental procedures and 1H NMR, 13C NMR spectra for all new compounds. See DOI: 10.1039/c2cc35721f
A common strategy for the stereoselective and protecting group-free total synthesis of the myxobacterial antibiotics myxothiazole Z, (14 S )-melithiazole G and (14 S )-cystothiazole F is described featuring an asymmetric organocatalytic transfer hydrogenation, a palladium-catalyzed Stille coupling a...
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| creator | Colon, Aude Hoffman, Thomas J Gebauer, Julian Dash, Jyotirmayee Rigby, James H Arseniyadis, Stellios Cossy, Janine |
| description | A common strategy for the stereoselective and protecting group-free total synthesis of the myxobacterial antibiotics myxothiazole Z, (14
S
)-melithiazole G and (14
S
)-cystothiazole F is described featuring an asymmetric organocatalytic transfer hydrogenation, a palladium-catalyzed Stille coupling and a cross-metathesis as the key steps.
A common strategy for the stereoselective total synthesis of the myxobacterial antibiotics myxothiazole Z, melithiazole G and cystothiazole F is described featuring an asymmetric organocatalytic transfer hydrogenation, a palladium-catalyzed Stille coupling and a cross-metathesis as the key steps. |
| doi_str_mv | 10.1039/c2cc35721f |
| format | Article |
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S
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S
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S
)-melithiazole G and (14
S
)-cystothiazole F is described featuring an asymmetric organocatalytic transfer hydrogenation, a palladium-catalyzed Stille coupling and a cross-metathesis as the key steps.
A common strategy for the stereoselective total synthesis of the myxobacterial antibiotics myxothiazole Z, melithiazole G and cystothiazole F is described featuring an asymmetric organocatalytic transfer hydrogenation, a palladium-catalyzed Stille coupling and a cross-metathesis as the key steps.</abstract><doi>10.1039/c2cc35721f</doi><tpages>3</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Catalysis-based enantioselective total synthesis of myxothiazole Z, (14S)-melithiazole G and (14S)-cystothiazole FElectronic supplementary information (ESI) available: Details of experimental procedures and 1H NMR, 13C NMR spectra for all new compounds. See DOI: 10.1039/c2cc35721f |
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