A general access to 1,1-cyclopropane aminoketones and their conversion into 2-benzoyl quinolinesElectronic supplementary information (ESI) available: Experimental procedure, 1H and 13C NMR spectra for all compounds. CCDC 885176. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2cc35235d

1,1-Cyclopropane aminoketones were efficiently synthesized in high yields by the tandem reaction of -amino aryl ketones with vinyl sulfonium salts using DBU as the base in CH 2 Cl 2 . This methodology was utilized to synthesize 2-benzoyl quinolines. 1,1-Cyclopropane aminoketones have been synthesize...

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Hauptverfasser: Mao, Zhenjun, Qu, Haijun, Zhao, Yanyan, Lin, Xufeng
Format: Artikel
Sprache:eng
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Zusammenfassung:1,1-Cyclopropane aminoketones were efficiently synthesized in high yields by the tandem reaction of -amino aryl ketones with vinyl sulfonium salts using DBU as the base in CH 2 Cl 2 . This methodology was utilized to synthesize 2-benzoyl quinolines. 1,1-Cyclopropane aminoketones have been synthesized from vinyl sulfonium and -amino aryl ketones, subsequent transformations lead to 2-benzoyl quinolines.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc35235d