Solvent-dependent amplification of chirality in assemblies of porphyrin trimers based on benzene tricarboxamideThis article is part of the ChemComm Porphyrins and phthalocyanines web themed issue.Electronic supplementary information (ESI) available: Experimental procedures and synthesis of porphyrin trimers 3 and 4. See DOI: 10.1039/c2cc31156a

Self-assembling achiral and chiral porphyrin trimers based on benzene tricarboxamide exhibit amplification of chirality only in solvents in which the assemblies are dynamic enough to rearrange their constituting components. Self-assembling achiral and chiral porphyrin trimers exhibit amplification o...

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Hauptverfasser: Veling, Nico, van Hameren, Richard, van Buul, Arend M, Rowan, Alan E, Nolte, Roeland J. M, Elemans, Johannes A. A. W
Format: Artikel
Sprache:eng
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Zusammenfassung:Self-assembling achiral and chiral porphyrin trimers based on benzene tricarboxamide exhibit amplification of chirality only in solvents in which the assemblies are dynamic enough to rearrange their constituting components. Self-assembling achiral and chiral porphyrin trimers exhibit amplification of chirality only in solvents where dynamic exchange of their components occurs.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31156a