Synthesis of highly porous borazine-linked polymers and their application to H2, CO2, and CH4 storageElectronic Supplementary Information (ESI) available: Experimental procedures, characterization methods, and gas sorption studies. See DOI: 10.1039/c1py00374g

The synthesis of highly porous borazine-linked polymers (BLPs) and their gas uptakes are reported. BLPs exhibit high surface areas up to 2866 m 2 g −1 and can store significant amounts of H 2 (1.93 wt%) and CO 2 (12.8 wt%) at 77 K and 273 K, respectively at 1.0 bar with respective isosteric heats of adsorption of 6.0 and 25.2 kJ mol −1 . The synthesis of highly porous borazine-linked polymers (BLPs) and their gas uptakes are reported. BLPs exhibit high surface area and can store significant amounts of H 2 and CO 2 with respective isosteric heats of adsorption of 6.0 and 25.2 kJ mol −1 .