Fabrication of electrochemically responsive surface relief diffraction gratings based on a multifunctional polyamide containing oligoaniline and azo groupsElectronic supplementary information (ESI) available. See DOI: 10.1039/c1jm14047g

A novel, well-defined multifunctional polyamide bearing pendent aniline tetramer groups has been synthesized via low temperature solution polycondensation. The simultaneous presence of these two functional groups allows the polyamide to display the properties of azo-chromophore and oligoaniline, such as photoinduced birefringence and reversible electroactivity. The electrochromic performance of the polyamide shows the optical change in absorptivity depends on the various redox states of oligoaniline upon electrochemical switching. It is well known that a change in absorptivity is accompanied by a concomitant change in refractive index. By taking advantage of this effect and using the single step fabrication of surface relief gratings based on azo-chromophore, we have fabricated optical diffraction gratings with which the diffraction efficiency can be modulated by an electrochemical signal. Although patterned electroactive films have been made by many techniques, the copolymer approach employing the simple one-step surface relief gratings process displays optimal properties with respect to modulation depth and convenience, which avoids complicated electropolymerization steps or photochemical reactions. The electrochemically-induced modulation in the diffraction efficiency of the polyamide is believed to arise primarily from the effect of the redox state on the film's refractive index. Electrochemically responsive diffraction gratings are prepared based on an electroactive azo copolymer employing the one-step photofabrication of SRGs.