Synthesis, characterization, and testing of supported Au catalysts prepared from atomically-tailored Au38(SC12H25)24 clustersElectronic supplementary information (ESI) available. See DOI: 10.1039/c1cp22438g

Nearly monodispersed Au 38 (SC 12 H 25 ) 24 clusters (1.7 0.2 nm) were synthesized using a modified Brust process while utilizing a thiol etching approach for the ligand exchange. HRTEM, MALDI, FTIR, and XAS analysis confirmed the formation of the 38-atom clusters in solution. This solution was used to impregnate a microporous TiO 2 support to give 0.7% Au 38 /TiO 2 catalyst. Subsequent drying in air and treatment with H 2 /He at 400 C removed most of the sulfur ligands, and also increased the Au cluster size to 3.9 0.96 nm. XPS and EXAFS analysis of this supported catalyst showed trace levels of residual sulfides, apparently located at the AuTiO 2 interface. CO oxidation tests on these supported clusters show an activation energy and range of TOFs comparable to those reported by others. These results suggest that supported Au clusters of controllable size can be prepared with this thiol-ligated solution-based method, providing a new approach to the synthesis of these catalysts. The synthesis of Au 38 (SC 12 H 25 ) 24 clusters in solution, and the use of these clusters as potential catalysts has been demonstrated.