Dual stimuli responsive PEG based hyperbranched polymersElectronic supplementary information (ESI) available: Experimental details and Fig. S1-S4. See DOI: 10.1039/c0py00101e

PEG based hyperbranched copolymers have been synthesised using a high concentration of ethylene glycol dimethacrylate (EGDMA) as the branching agent (up to 10% molar ratio of total feed monomers) via a new in situ deactivation enhanced atom transfer radical polymerisation (DE-ATRP). These hyperbranc...

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Hauptverfasser: Dong, Yixiao, Gunning, Paul, Cao, Hongliang, Mathew, Asha, Newland, Ben, Saeed, Aram Omer, Magnusson, Johannes Pall, Alexander, Cameron, Tai, Hongyun, Pandit, Abhay, Wang, Wenxin
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container_title
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creator Dong, Yixiao
Gunning, Paul
Cao, Hongliang
Mathew, Asha
Newland, Ben
Saeed, Aram Omer
Magnusson, Johannes Pall
Alexander, Cameron
Tai, Hongyun
Pandit, Abhay
Wang, Wenxin
description PEG based hyperbranched copolymers have been synthesised using a high concentration of ethylene glycol dimethacrylate (EGDMA) as the branching agent (up to 10% molar ratio of total feed monomers) via a new in situ deactivation enhanced atom transfer radical polymerisation (DE-ATRP). These hyperbranched copolymers exhibited a lower critical solution temperature (LCST) close to body temperature and photo-crosslinkable behavior. Thermoresponsive and photo-crosslinkable PEG based hyperbranched polymers with LCST around 37 °C were prepared via an in situ deactivation enhanced ATRP.
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title Dual stimuli responsive PEG based hyperbranched polymersElectronic supplementary information (ESI) available: Experimental details and Fig. S1-S4. See DOI: 10.1039/c0py00101e
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