Continuous carbide-derived carbon films with high volumetric capacitance

Monolithic porous carbon film has a great potential for integrated supercapacitors due to no polymer binder, reduced macropore volume, and good adhesion between current collector and active material. It is demonstrated that continuous carbide-derived carbon (CDC) films can be synthesized on various substrates by dry etching. CDC films show high volumetric capacitance of ∼180 F cm −3 in 1.5 M TEABF 4 /acetonitrile electrolyte. Continuous carbide-derived carbon film electrodes were synthesized and showed excellent volumetric capacitance of 180 F cm −3 , about three times higher than that of conventional supercapacitor electrodes in organic electrolytes.