Dually responsive aqueous gels from thermo- and light-sensitive hydrophilic ABA triblock copolymersElectronic supplementary information (ESI) available: Temperature ramp for a 10.0 wt% aqueous solution of ABA-1; frequency dependences of G′ and G′′ of a 10.0 wt% aqueous solution of ABA-3 after UV irradiation at 41, 48, and 65 °C; temperature ramps for aqueous solutions of ABA-3 with concentrations of 14.2, 10.0, 6.0, 4.0, and 3.0 wt%; temperature ramps for aqueous solutions of irradiated ABA-3 wi

We report in this article the synthesis of a series of thermo- and light-sensitive hydrophilic ABA linear triblock copolymers, poly(ethoxytri(ethylene glycol) acrylate- co - o -nitrobenzyl acrylate)- b -poly(ethylene oxide)- b -poly(ethoxytri(ethylene glycol) acrylate- co - o -nitrobenzyl acrylate)...

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Hauptverfasser: Woodcock, Jeremiah W, Wright, Roger A. E, Jiang, Xueguang, O'Lenick, Thomas G, Zhao, Bin
Format: Artikel
Sprache:eng
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Zusammenfassung:We report in this article the synthesis of a series of thermo- and light-sensitive hydrophilic ABA linear triblock copolymers, poly(ethoxytri(ethylene glycol) acrylate- co - o -nitrobenzyl acrylate)- b -poly(ethylene oxide)- b -poly(ethoxytri(ethylene glycol) acrylate- co - o -nitrobenzyl acrylate) (P(TEGEA- co -NBA)- b -PEO- b -P(TEGEA- co -NBA)), with various NBA molar contents and the study of sol-gel transitions of their aqueous solutions. The copolymers were prepared by ATRP from a difunctional PEO macroinitiator; the polydispersity indexes of all polymers were
ISSN:1744-683X
1744-6848
DOI:10.1039/c000450b