Dually responsive aqueous gels from thermo- and light-sensitive hydrophilic ABA triblock copolymersElectronic supplementary information (ESI) available: Temperature ramp for a 10.0 wt% aqueous solution of ABA-1; frequency dependences of G′ and G′′ of a 10.0 wt% aqueous solution of ABA-3 after UV irradiation at 41, 48, and 65 °C; temperature ramps for aqueous solutions of ABA-3 with concentrations of 14.2, 10.0, 6.0, 4.0, and 3.0 wt%; temperature ramps for aqueous solutions of irradiated ABA-3 wi
We report in this article the synthesis of a series of thermo- and light-sensitive hydrophilic ABA linear triblock copolymers, poly(ethoxytri(ethylene glycol) acrylate- co - o -nitrobenzyl acrylate)- b -poly(ethylene oxide)- b -poly(ethoxytri(ethylene glycol) acrylate- co - o -nitrobenzyl acrylate)...
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | We report in this article the synthesis of a series of thermo- and light-sensitive hydrophilic ABA linear triblock copolymers, poly(ethoxytri(ethylene glycol) acrylate-
co
-
o
-nitrobenzyl acrylate)-
b
-poly(ethylene oxide)-
b
-poly(ethoxytri(ethylene glycol) acrylate-
co
-
o
-nitrobenzyl acrylate) (P(TEGEA-
co
-NBA)-
b
-PEO-
b
-P(TEGEA-
co
-NBA)), with various NBA molar contents and the study of sol-gel transitions of their aqueous solutions. The copolymers were prepared by ATRP from a difunctional PEO macroinitiator; the polydispersity indexes of all polymers were |
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ISSN: | 1744-683X 1744-6848 |
DOI: | 10.1039/c000450b |