Total synthesis of trioxilins 11,12-threo-(8,11,12)-A3 through type B3 trioxilins

The total synthesis of trioxilins 11,12- threo -TrXB 3 has been extended to the corresponding trioxilins of the (8,11,12)-A 3 type. The synthesis involves the allylic rearrangement of a protected TrXB 3 derivative with a free 10-hydroxyl group under the Mitsunobu reaction conditions as the key step.

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Bibliographische Detailangaben
Veröffentlicht in:	Mendeleev communications 2004, Vol.14 (6), p.291-293
Hauptverfasser:	Lapitskaya, Margarita A, Vasiljeva, Ljudmila L, Demin, Peter M, Pivnitsky, Kasimir K
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The total synthesis of trioxilins 11,12- threo -TrXB 3 has been extended to the corresponding trioxilins of the (8,11,12)-A 3 type. The synthesis involves the allylic rearrangement of a protected TrXB 3 derivative with a free 10-hydroxyl group under the Mitsunobu reaction conditions as the key step.
ISSN:	0959-9436 1364-557X
DOI:	10.1070/MC2004v014n06ABEH002004