New cationic clathrate: synthesis and structure of [Si40P6]I6.5
The [Si 40 P 6 ]I 6.5 cationic clathrate possessing the type-I clathrate structure with a minimal known unit-cell volume and a remarkably high vacancy concentration in the guest sublattice was synthesised.
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| Veröffentlicht in: | Mendeleev communications 2004, Vol.14 (4), p.135-136 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The [Si
40
P
6
]I
6.5
cationic clathrate possessing the type-I clathrate structure with a minimal known unit-cell volume and a remarkably high vacancy concentration in the guest sublattice was synthesised. |
|---|---|
| ISSN: | 0959-9436 1364-557X |
| DOI: | 10.1070/MC2004v014n04ABEH001945 |