Vertical organic electrochemical transistors for complementary circuits

Organic electrochemical transistors (OECTs) and OECT-based circuitry offer great potential in bioelectronics, wearable electronics and artificial neuromorphic electronics because of their exceptionally low driving voltages (50,000 cycles) are achieved in, to our knowledge, the first vertically stacked complementary vertical OECT logic circuits. This architecture opens many possibilities for fundamental studies of organic semiconductor redox chemistry and physics in nanoscopically confined spaces, without macroscopic electrolyte contact, as well as wearable and implantable device applications. Vertical organic electrochemical transistors demonstrating unprecedented performances in both p- and n-type operation modes have been synthesized from new electro-active and ion-permeable semiconducting polymers by the interface engineering of electro-active blend layers.