Crystal structure of 2-(morpholino)ethyl-ammonium picrate monohydrate

The title compound, C H N O ·C H N O ·H O, was synthesized slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C H N O) , one anion (C H N O ) and a water mol-ecule in the asymmetric unit. The morpholine ring in the cation ado...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-01, Vol.79 (Pt 1), p.8-13
Hauptverfasser: Chidambaranathan, Balasubramanian, Sivaraj, Settu, Selvakumar, Shanmugam
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Sprache:eng
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Zusammenfassung:The title compound, C H N O ·C H N O ·H O, was synthesized slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C H N O) , one anion (C H N O ) and a water mol-ecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C-H⋯O, O-H⋯O, O-H⋯N and N-H⋯O hydrogen-bonding inter-actions and π-π stacking. The inter-molecular inter-actions of the synthesized compound were qu-anti-fied by Hirshfeld surface analysis.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989022011409