Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage

Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage

Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates.

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Veröffentlicht in:RSC advances 2022-09, Vol.12 (39), p.25280-25283
Hauptverfasser: Liu, Huijin, Sun, Kai, Li, Xiaolan, Zhang, Jie, Lu, Wei, Luo, Xuzhong, Luo, Haiqing
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Cleavage
Palladium
Phosphorylation
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Zusammenfassung:Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates.
ISSN:2046-2069
2046-2069
DOI:10.1039/d2ra04297e