Ultrafine platinum nanoparticles supported on N,S-codoped porous carbon nanofibers as efficient multifunctional materials for noticeable oxygen reduction reaction and water splitting performance

The design of highly active, stable and durable platinum-based electrocatalysts towards the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and hydrogen adsorption has a high and urgent demand in fuel cells, water splitting and hydrogen storage. Herein, ultrafine platinum nanoparticles (Pt NPs) supported on N,S-codoped porous carbon nanofibers (Pt-N,S-pCNFs) hybrids were prepared through the electrospinning method coupled with hydrothermal and carbonation processes. The ultrafine Pt NPs are sufficiently dispersed and loaded on pCNFs and codoped with N and S, which can improve oxygen adsorption, afford more active sites, and greatly enhance electron mobility. The Pt-N,S-pCNFs hybrid achieves excellent activity and stability for ORR with ∼70 mV positive shift of onset potential compared to the commercial Pt/C-20 wt% electrocatalyst. The long-term catalytic durability with 89.5% current retention after a 10 000 s test indicates its remarkable ORR behavior. Pt-N,S-pCNFs also exhibits excellent HER and OER performance, and can be used as an efficient catalyst for water splitting. In addition, Pt-N,S-pCNFs exhibits an excellent hydrogen storage capacity of 0.76 wt% at 20 °C and 10 MPa. This work provides novel design strategies for the development of multifunctional materials as high-performance ORR catalysts, water splitting electrocatalysts and hydrogen storage materials. Ultrafine platinum nanoparticles supported on N,S-codoped porous carbon nanofibers (Pt-N,S-pCNFs) hybrids achieve excellent activity and stability for ORR, HER and OER and also show high hydrogen storage capacity.