Development of Highly Luminescent Water-Insoluble Carbon Dots by Using Calix[4]pyrrole as the Carbon Precursor and Their Potential Application in Organic Solar Cells

Carbon dots (CDs) are carbon-based fluorescent nanomaterials that are of interest in different research areas due to their low cost production and low toxicity. Considering their unique photophysical properties, hydrophobic/amphiphilic CDs are powerful alternatives to metal-based quantum dots in LED...

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Veröffentlicht in:ACS omega 2022-06, Vol.7 (22), p.18840-18851
Hauptverfasser: Coşkun, Yağız, Ünlü, Fatma Yelda, Yılmaz, Tuğbahan, Türker, Yurdanur, Aydogan, Abdullah, Kuş, Mahmut, Ünlü, Caner
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Sprache:eng
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Zusammenfassung:Carbon dots (CDs) are carbon-based fluorescent nanomaterials that are of interest in different research areas due to their low cost production and low toxicity. Considering their unique photophysical properties, hydrophobic/amphiphilic CDs are powerful alternatives to metal-based quantum dots in LED and photovoltaic cell designs. On the other hand, CDs possess a considerably high amount of surface defects that give rise to two significant drawbacks: (1) causing decrease in quantum yield (QY), a crucial drawback that limits their utilization in LEDs, and (2) affecting the efficiency of charge transfer, a significant factor that limits the use of CDs in photovoltaic cells. In this study, we synthesized highly luminescent, water-insoluble, slightly amphiphilic CDs by using a macrocyclic compound, calix[4]­pyrrole, for the first time in the literature. Calix[4]­pyrrole-derived CDs (CP-DOTs) were highly luminescent with a QY of over 60% and size of around 4–10 nm with graphitic structure. The high quantum yield of CP-DOTs indicated that they had less amount of surface defects. Furthermore, CP-DOTs were used as an additive in the active layer of organic solar cells (OSC). The photovoltaic parameters of OSCs improved upon addition of CDs. Our results indicated that calix[4]­pyrrole is an excellent carbon precursor to synthesize highly luminescent and water-insoluble carbon dots, and CDs derived from calix[4]­pyrrole are excellent candidates to improve optoelectronic devices.
ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.2c01795