N2-selective alkylation of NH-1,2,3-triazoles with vinyl ethers via gold catalysis
A new method was developed to synthesize N2-alkyl-substituted 1,2,3-triazoles via gold catalyzed alkylation of vinyl ethers with mono- and unsubstituted NH-1,2,3-triazoles and benzotriazole. A hydrogen bond between the oxygen atom of the vinyl ethers, activated via the gold catalyst, and the NH-1,2,...
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| Veröffentlicht in: | RSC advances 2018-08, Vol.8 (49), p.27610-27615 |
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| container_end_page | 27615 |
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| container_issue | 49 |
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| container_title | RSC advances |
| container_volume | 8 |
| creator | Luo, Guoli Sun, Chenyang Li, Yan Li, Xiaoxiao Zhao, Zhigang |
| description | A new method was developed to synthesize N2-alkyl-substituted 1,2,3-triazoles via gold catalyzed alkylation of vinyl ethers with mono- and unsubstituted NH-1,2,3-triazoles and benzotriazole. A hydrogen bond between the oxygen atom of the vinyl ethers, activated via the gold catalyst, and the NH-1,2,3-triazoles was supposed to be generated, which selectively gave the N2-alkylation products. |
| doi_str_mv | 10.1039/c8ra04790a |
| format | Article |
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A hydrogen bond between the oxygen atom of the vinyl ethers, activated via the gold catalyst, and the NH-1,2,3-triazoles was supposed to be generated, which selectively gave the N2-alkylation products.</description><subject>Alkylation</subject><subject>Benzotriazole</subject><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Ethers</subject><subject>Gold</subject><subject>Hydrogen bonds</subject><subject>Triazoles</subject><subject>Vinyl ethers</subject><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkE9LAzEQxYMgttRe_AQLXjx0NX822eQiSFErlAqi55DNZtvUdFOTbGX99K7Yi87lMczwe28GgAsErxEk4kbzoGBRCqhOwBjDguUYMjEC0xi3cChGEWboDIwIpQUucTkGLyucR-OMTvZgMuXee6eS9W3mm2y1yNEMz0ieglVf3pmYfdq0yQ627V1m0saEODQqW3tXZ1ol5fpo4zk4bZSLZnrUCXh7uH-dL_Ll8-PT_G6Z7xHFKi-xhhXURIjK6GpIwxhEDCNmakSMEJox3ZSEI0UY0kJjzA1hglW8bhjVJZmA21_uvqt2ptamTUE5uQ92p0IvvbLy76S1G7n2BykgJ1zwAXB1BAT_0ZmY5M5GbZxTrfFdlEMiTAtB4Y_X5b_Vre9CO5wnMeRFMfyVU_INoyh1JA</recordid><startdate>20180802</startdate><enddate>20180802</enddate><creator>Luo, Guoli</creator><creator>Sun, Chenyang</creator><creator>Li, Yan</creator><creator>Li, Xiaoxiao</creator><creator>Zhao, Zhigang</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20180802</creationdate><title>N2-selective alkylation of NH-1,2,3-triazoles with vinyl ethers via gold catalysis</title><author>Luo, Guoli ; Sun, Chenyang ; Li, Yan ; Li, Xiaoxiao ; Zhao, Zhigang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p152a-72c0b0c399becb27266016216ed13e99c66cf7381a361c9c228e3696b8df65c73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alkylation</topic><topic>Benzotriazole</topic><topic>Catalysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Ethers</topic><topic>Gold</topic><topic>Hydrogen bonds</topic><topic>Triazoles</topic><topic>Vinyl ethers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luo, Guoli</creatorcontrib><creatorcontrib>Sun, Chenyang</creatorcontrib><creatorcontrib>Li, Yan</creatorcontrib><creatorcontrib>Li, Xiaoxiao</creatorcontrib><creatorcontrib>Zhao, Zhigang</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luo, Guoli</au><au>Sun, Chenyang</au><au>Li, Yan</au><au>Li, Xiaoxiao</au><au>Zhao, Zhigang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>N2-selective alkylation of NH-1,2,3-triazoles with vinyl ethers via gold catalysis</atitle><jtitle>RSC advances</jtitle><date>2018-08-02</date><risdate>2018</risdate><volume>8</volume><issue>49</issue><spage>27610</spage><epage>27615</epage><pages>27610-27615</pages><eissn>2046-2069</eissn><abstract>A new method was developed to synthesize N2-alkyl-substituted 1,2,3-triazoles via gold catalyzed alkylation of vinyl ethers with mono- and unsubstituted NH-1,2,3-triazoles and benzotriazole. 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| ispartof | RSC advances, 2018-08, Vol.8 (49), p.27610-27615 |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Alkylation Benzotriazole Catalysis Chemical synthesis Chemistry Ethers Gold Hydrogen bonds Triazoles Vinyl ethers |
| title | N2-selective alkylation of NH-1,2,3-triazoles with vinyl ethers via gold catalysis |
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